Located in a picturesque area of Lisbon, with great views of the Tagus river the National Museum of Art is interesting even to take a look from outside (also, a great cafetaria in a garden inside, with free access).
From Wikipedia:
"The Museum has its roots in the 1833 abolition of religious orders and confiscation of the monasteries in Portugal, which brought a trove of religious art and ornaments into the public sphere. At the instigation of the liberal politician Passos Manuel, the Academia de Bellas Artes ("Academy of Fine Arts") was founded in 1836, and established its headquarters at the former monastery of São Francisco da Cidade (near the Chiado, in Lisbon). Although primarily dedicated to nurturing new artists, that same year, the Academia founded the Galeria Nacional de Pintura ("National Gallery of Painting") on the lower levels of the same building, as a subsidiary division to select, care for and display some of the better pieces of the expropriated monastic art then in government storage. An Academia panel selected some 540 paintings for the Galeria. Predictably, most of these were religious-oriented pieces of Portuguese origin.
In the chaos and aftermath of the Portuguese Liberal Wars, some of the private art collections of ruined noble families were expropriated or found their way on to the market. Of particular significance was the painting collection of the disgraced former queen, the late Carlota Joaquina, which was acquired by the Portuguese government and given to the Academia in 1859.[1] The former king Ferdinand II of Portugal, a connoisseur of fine arts, took an interest in the budding organization, secured its royal sponsorship (it was renamed Academia Real de Belas Artes in 1862) and, in 1865-67, Ferdinand II made a series of substantial cash donations, giving the Galeria an independent acquisition budget, enabling it to purchase pieces on the art market.
On the initiative of Francisco de Sousa Holstein (1st Marquis of Sousa Holstein), a vice-inspector of the Academia Real, in 1868, the Galeria's rooms were remodelled into a better exhibition space for its expanding collection and opened to the general public.[1] Nonetheless, the facilities remained inadequate - it was terribly humid, cramped and still traversed by unrelated visitors to the Academia (which had, by now, become something of a social hang-out for dissheveled bohemian artists and students). In 1875, a commission headed by Sousa Holstein recommended the founding of a larger and more pemanent museum away from the Academia's Chiado building.
In 1881, the Academia's educational division was split off and turned into the Escola Real de Belas-Artes ("Royal School of Fine Arts", now part of the University of Lisbon), with the Academia Real de Belas-Artes proper limited to cultural pursuits.
In 1881, Academia officer Delfim Guedes rented the 17th-century Palace of Janelas Verdes ("Green Windows"), the former Lisbon residence of the Counts of Alvor that had been seized by the Marquis of Pombal after 1759 and sold to his own brother, the Cardinal-Inquisitor Paulo António de Carvalho e Mendonça (thus it is also known as the Palace of Pombal-Alvor). Later sold to the neighboring Carmelite convent of Santo Alberto, the palace returned to private hands following the 1833 dissolution. Guedes intended to use it as a temporary space for an international exhibition on Iberian ornamental art ("Exposição Retrospectiva de Arte Ornamental Portuguesa e Espanhola") organized by the South Kensington Museum (now the Victoria & Albert) in London, that was set to visit Lisbon in 1882. The government formally purchased the Janelas Verdes palace in June, 1884, and recast it as the Museu Nacional de Belas-Artes e Arqueologia ("National Museum of Fine Arts and Archaeology"), formally founded on 11 May 1884, to house what where then known as the "Museus Centrais" of the State and placed it under the management of the Academia Real.
Following the republican 1910 revolution, the arrangement was overhauled and the museum's management stopped depending on the Academia Real (now renamed Academia Nacional de Belas Artes). By a decree of 26 May 1911, the collections were split up and two separate and independent museums created - the Museu Nacional de Arte Antiga ("National Museum of Ancient Art"), at the Palace of Janelas Verdes, and the Museu Nacional de Arte Contemporânea" ("National Museum of Contemporary Art") at the old location of the Academia's Galeria at São Francisco da Cidade (since renamed the Chiado Museum). The latter collection's cut-off date was roughly 1850, everything prior to that assigned to Arte Antiga.
The MNAA's first museum director was the energetic José de Figueiredo, who promptly began reforming the museum based on the latest planning and exhibition principles and re-orienting it decisively towards painting. Figueiredo was the first to study and identify the authorship and significance of Saint Vincent Panels, a 15th-century polyptych discovered c. 1882 and attributed by Figueiredo to Nuno Gonçalves. The St. Vincent panels were installed in the museum by 1916 and remain perhaps its best known piece.
In 1940, the MNAA expanded its installations by acquiring the neighboring old convent of Santo Alberto and turned it into an annex connected by a footbridge. The chapel of the convent, a fine example of 18th Portuguese Baroque art and architecture, was incorporated into the exhibits."
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